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I couldn't shake the feeling that it was Sour Grapes: The Book while reading it.
*cue disappointment of people who google Radical Atheism and find out that this isn't a chance to attack/defend Richard Dawkins*
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I suppose so, evidently a sizable portion of atheists became atheists after becoming strained with the religion they grew up in, especially more fundamentalist or evangelical religious communities. No idea about the specific book though.
The book's about Derrida.